Pore space partition and charge separation in cage-within-cage indium-organic frameworks with high CO2 uptake.
نویسندگان
چکیده
The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 48 شماره
صفحات -
تاریخ انتشار 2010